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Royal Society of Chemistry, Dalton Transactions, 23(49), p. 7692-7696, 2020

DOI: 10.1039/d0dt01262a

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Strong magnetic coupling of spins in Fe(II) dimers with differently charged thioindigo ligands

Journal article published in 2020 by Dmitri V. Konarev ORCID, Alexey V. Kuz`min, Alexey V. Kuzmin, Mikhail S. Batov ORCID, Salavat S. Khasanov, Akihiro Otsuka ORCID, Hideki Yamochi ORCID, Hiroshi Kitagawa ORCID, Rimma N. Lyubovskaya
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Coordination complex of iron(ii) with radical anion and dianion of thioindigo {[2.2.2]cryptand(K+)}2{FeII(TI˙−)(TI2−)}2·2C6H4Cl2 (1) is obtained. Complex has two high-spin FeII centers separated by oxygen atoms, and two TI˙− radical anions coordinated to FeII.