Published in
Royal Society of Chemistry, Chemical Communications, 59(56), p. 8182-8185, 2020
DOI: 10.1039/d0cc01699c
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A tetranuclear nickel cluster isolated in multiple high-valent states
Journal article published in 2020 by
Samuel I. Jacob,
Iskander Douair 
,
Guang Wu,
Laurent Maron ,
Gabriel Ménard
,
Guang Wu,
Laurent Maron ,
Gabriel Ménard
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Abstract
An all Ni(iii) tetranuclear cluster is isolated. Metal-centered oxidations are proposed for it and its mixed-valent congeners, supported by crystallographic, spectroscopic, and computational methods.