Published in
Royal Society of Chemistry, Organic and Biomolecular Chemistry, 13(18), p. 2392-2397, 2020
DOI: 10.1039/d0ob00198h
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Metal-free synthesis of imino-disaccharides and calix-iminosugars by photoinduced radical thiol–ene coupling (TEC)
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Abstract
Deprotected iminosugar alkenes were subjected to thiol–ene coupling with deprotected sugar thiols to afford new imino-disaccharides. Two thiol–ene couplings converted these alkenes into iminosugar thiols and then multivalent iminosugars.