Published in
Royal Society of Chemistry, Organic and Biomolecular Chemistry, 9(18), p. 1754-1759, 2020
DOI: 10.1039/d0ob00044b
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Carbonylative Suzuki–Miyaura couplings of sterically hindered aryl halides: synthesis of 2-aroylbenzoate derivatives
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Abstract
A new protocol for carbonylative coupling of sterically hindered aryl bromides with boronic acids featuring slow addition of the boronic acid as a strategy to suppress unwanted non-carbonylative couplings for sterically hindered aryl bromides.