Published in
Royal Society of Chemistry, New Journal of Chemistry, 9(44), p. 3748-3754, 2020
DOI: 10.1039/c9nj04591k
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Manganese(ii) complex of an oxygen–nitrogen donor Schiff base ligand showing efficient catechol oxidase activity: synthesis, spectroscopic and kinetic study
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Abstract
A Mn(ii) complex containing two tridentate O,N,O-donor semicarbazone ligands shows very high catalytic activity for the aerial oxidation of 3,5DTBCH2 with kcat = 3.10 × 106 h−1, and kcat/KM = 3.25 × 108 h−1 M−1.