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Royal Society of Chemistry, Dalton Transactions, 6(49), p. 1981-1991, 2020
DOI: 10.1039/c9dt04873a
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Aerobic dehydrogenation of amines to nitriles catalyzed by triazolylidene ruthenium complexes with O2 as terminal oxidant
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Abstract
Pyridyl-substituted mesoionic triazolylidene ruthenium cymene complexes catalyze the oxidation of both aromatic and aliphatic amines to nitriles with high activity and selectivity under benign conditions using dioxygen as the terminal oxidant.