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Royal Society of Chemistry, Chemical Communications, 20, p. 2860

DOI: 10.1039/b901893j

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An intensely and oxygen independent phosphorescent gold(I)–silver(I) complex: trapping an Au8Ag10 oligomer by two gold-alkynyl-diphosphine molecules

Journal article published in 2009 by Igor O.; Lin Yi-Chih; Karttunen Antti J.; Haukka Matti; Chou Pi-Tai; Tunik Sergey P.; Pakkanen Tapani A. Koshevoy, Yi-Chih Lin, Antti J. Karttunen, Matti Haukka, Pi-Tai Chou ORCID, Sergey P. Tunik, Tapani A. Pakkanen
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Abstract

The molecular heterometallic [{Au(8)Ag(10)(C(2)Ph)(16)}{(PhC(2)Au)(2)PPh(2)(C(6)H(4))(3)PPh(2)}(2)](2+) aggregate of unprecedented topology was obtained and structurally characterized; this compound demonstrates unusually effective phosphorescence, which displays negligible oxygen quenching due to shielding of emissive central cluster by the outer shell of the molecule.