Published in
Royal Society of Chemistry, Organic and Biomolecular Chemistry, 3(18), p. 538-550, 2020
DOI: 10.1039/c9ob02411e
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Selective synthesis of trisubstituted pyrroles through the reactions of alkynyl Fischer carbene complexes with oxazolones
Journal article published in 2020 by
Julio López 
,
Iván Velazco-Cabral ,
Eloy Rodríguez-Deleón ,
Clarisa Villegas Gómez ,
Francisco Delgado ,
Joaquín Tamariz ,
Ana Arrieta ,
Fernando P. Cossío ,
Miguel A. Vázquez
,
Iván Velazco-Cabral ,
Eloy Rodríguez-Deleón ,
Clarisa Villegas Gómez ,
Francisco Delgado ,
Joaquín Tamariz ,
Ana Arrieta ,
Fernando P. Cossío ,
Miguel A. Vázquez
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Abstract
The unexpected reactivity of fluorinated oxazolones with alkynyl Fischer carbenes is reported. The loss of the –CF3 and a cascade process involving nucleophilic additions were observed.