Relative hemilabilities of H2B(az)2 (az = pyrazolyl, dimethylpyrazolyl, methimazolyl) chelates in the complexes [M(η-C3H5)(CO)2{H2B(az)2}] (M = Mo, W)

Abernethy, Robyn J.; Foreman, Mark R. St.-J.; Hill, Anthony F.; Smith, Matthew K.; Willis, Anthony C.

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Royal Society of Chemistry, Dalton Transactions, 3(49), p. 781-796, 2020

DOI: 10.1039/c9dt03744f

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Relative hemilabilities of H2B(az)2 (az = pyrazolyl, dimethylpyrazolyl, methimazolyl) chelates in the complexes [M(η-C3H5)(CO)2{H2B(az)2}] (M = Mo, W)

Journal article published in 2020 by Robyn J. Abernethy, Mark R. St.-J. Foreman

, Anthony F. Hill

, Matthew K. Smith, Anthony C. Willis

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Abstract

The question of B–H–Mo hemilability in a range of dihydrobis(azolyl)borate scorpionate ligands is discussed with reference to η³-allyl complexes [Mo(η³-C₃H₅)(CO)₂{H₂B(az)₂}] [az = pyrazolyl (pz), dimethylpyrazolyl (pz*), mercaptoimidazolyl (mt)].

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Relative hemilabilities of H2B(az)2 (az = pyrazolyl, dimethylpyrazolyl, methimazolyl) chelates in the complexes [M(η-C3H5)(CO)2{H2B(az)2}] (M = Mo, W)

Abstract