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Royal Society of Chemistry, Polymer Chemistry, 1(11), p. 34-38, 2020

DOI: 10.1039/c9py01485c

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The blocky structure of Ziegler–Natta “random” copolymers: myths and experimental evidence

Journal article published in 2020 by Claudio De Rosa ORCID, Odda Ruiz de Ballesteros ORCID, Rocco Di Girolamo ORCID, Anna Malafronte ORCID, Finizia Auriemma ORCID, Giovanni Talarico ORCID, Miriam Scoti ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

When Ziegler–Natta catalysts synthesize “random” copolymers, they give multiblocks copolymers. Chains of butene–ethylene copolymers contain blocks with long and short butene sequences that crystallize in forms II and I of iPB, respectively.