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Published in

Inorganic Chemistry Frontiers, 1(7), p. 117-127, 2020

DOI: 10.1039/c9qi01009b

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Structural, electrochemical and photophysical behavior of Ru(ii) complexes with large bite angle sulfur-bridged terpyridyl ligands

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Sulfur-bridged terpyridyl ligands expand the bite angles in Ru(ii) species leading to geometries very close to that of a “perfect” octahedron. Altering the donor strength of substituents results in systematic tuning of the redox properties.