Published in
Royal Society of Chemistry, Dalton Transactions, 42(48), p. 15888-15895, 2019
DOI: 10.1039/c9dt03008e
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Structural isomerism in the [(Ni@Sn9)In(Ni@Sn9)]5− Zintl ion
Journal article published in 2019 by
Chao Zhang,
Harry W. T. Morgan 
,
Zi-Chuan Wang ,
Chao Liu,
Zhong-Ming Sun ,
John E. McGrady
,
Zi-Chuan Wang ,
Chao Liu,
Zhong-Ming Sun ,
John E. McGrady
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Abstract
A new Zintl cluster, [(Ni@Sn9)In(Ni@Sn9)]5−, has been isolated in two distinct isomeric forms, one where both Ni@Sn9 units are coordinated to the bridging indium atom in an η3- mode, the other where one is η3- and the other η4-.