Published in
Royal Society of Chemistry, Polymer Chemistry, 36(10), p. 4944-4953, 2019
DOI: 10.1039/c9py00925f
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Guanidine as inexpensive dual function ligand and reducing agent for ATRP of methacrylates
Journal article published in 2019 by
Madson R. E. Santos,
Sílvia M. Ferreira,
Patrícia V. Mendonça 
,
Francesco De Bon,
Armenio C. Serra,
Jorge F. J. Coelho
,
Francesco De Bon,
Armenio C. Serra,
Jorge F. J. Coelho
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Abstract
N,N,N′,N′-Tetramethyl guanidine, an inexpensive and commercially available organic base, is used for the first time as ligand without any chemical modification for the supplemental activator and reducing agent atom transfer radical polymerization.