Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics, 36(21), p. 19755-19763, 2019
DOI: 10.1039/c9cp02914a
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The direct observation of the doorway 1nπ* state of methylcinnamate and hydrogen-bonding effects on the photochemistry of cinnamate-based sunscreens
Journal article published in 2019 by
Shin-Nosuke Kinoshita,
Yoshiya Inokuchi 
,
Yuuki Onitsuka,
Hiroshi Kohguchi,
Nobuyuki Akai,
Takafumi Shiraogawa ,
Masahiro Ehara ,
Kaoru Yamazaki,
Yu Harabuchi,
Satoshi Maeda ,
Takayuki Ebata
,
Yuuki Onitsuka,
Hiroshi Kohguchi,
Nobuyuki Akai,
Takafumi Shiraogawa ,
Masahiro Ehara ,
Kaoru Yamazaki,
Yu Harabuchi,
Satoshi Maeda ,
Takayuki Ebata
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Abstract
The electronic states and photochemistry including nonradiative decay (NRD) and trans(E) → cis(Z) isomerization of methylcinnamate (MC) and its hydrogen-bonded complex with methanol have been investigated under jet-cooled conditions.