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Royal Society of Chemistry, Organic and Biomolecular Chemistry, 35(17), p. 8185-8193, 2019

DOI: 10.1039/c9ob01589b

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Are one-step aromatic nucleophilic substitutions of non-activated benzenes concerted processes?

Journal article published in 2019 by Luis R. Domingo ORCID, Mar Ríos-Gutiérrez ORCID, Eduardo Chamorro ORCID, Patricia Pérez ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Analysis of the mechanism of one-step SNAr reactions of non-activated benzenes shows the presence of structures similar to those of Meisenheimer intermediates, thus accounting for the non-concerted nature of these reactions.