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Royal Society of Chemistry, Chemical Communications, 65(55), p. 9677-9680, 2019

DOI: 10.1039/c9cc03825f

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Selective mono- and dimetallation of a group 3 sandwich complex

Journal article published in 2019 by Antonio J. Martínez-Martínez ORCID, Alan R. Kennedy ORCID, Valerie Paprocki, Felipe Fantuzzi ORCID, Rian D. Dewhurst ORCID, Charles T. O’Hara ORCID, Holger Braunschweig ORCID, Robert E. Mulvey ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

While lithium alkyls and lithium amides do not metallate the scandium compound [(η5-C5H5)Sc(η8-C8H8)], a synergistic lithium–aluminium base-trap partnership cannot resist taking a bite with one C–H bond selectively cleaved from both Cp and COT rings.