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Royal Society of Chemistry, Chemical Communications, 64(55), p. 9523-9526, 2019

DOI: 10.1039/c9cc03316e

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Unexpected linkage isomerism in chiral tetranuclear bis-tridentate (1,2,3-triazol-4-yl)-picolinamide (tzpa) grids

Journal article published in 2019 by Isabel N. Hegarty, Hannah L. Dalton, Adam F. Henwood, Chris S. Hawes ORCID, Thorfinnur Gunnlaugsson ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Two chiral [2 × 2] tetranuclear CuII square grid complexes are prepared from a (1,2,3-triazol-4-yl)-picolinamide (tzpa) ligand. Linkage isomerism through the amide is observed accompanying an in situ deprotonation and CuI → CuII oxidation process.