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Royal Society of Chemistry, Dalton Transactions, 31(48), p. 11862-11871, 2019

DOI: 10.1039/c9dt02503k

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Co-existence of ferro- and antiferromagnetic interactions in a hexanuclear mixed-valence CoIII2MnII2MnIV2 cluster sustained by a multidentate Schiff base ligand

Journal article published in 2019 by Oleh Stetsiuk, Valentyn Synytsia, Svitlana R. Petrusenko, Vladimir N. Kokozay ORCID, Abdelkrim El-Ghayoury ORCID, Joan Cano ORCID, Francesc Lloret ORCID, Miguel Julve ORCID, Benoit Fleury ORCID, Narcis Avarvari ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

An unprecedented mixed-valence CoIII2MnII2MnIV2 cluster has been synthesized. Magnetochemical investigations combined with DFT calculations demonstrate the co-existence of antiferro- and ferromagnetic interactions within the MnIV2MnII2 core.