Published in
Royal Society of Chemistry, Organic and Biomolecular Chemistry, 30(17), p. 7155-7160, 2019
DOI: 10.1039/c9ob00593e
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Diversion of the Arbuzov reaction: alkylation of C–Cl instead of phosphonic ester formation on the fullerene cage
Journal article published in 2019 by
Ol'ga A. Kraevaya,
Alexander S. Peregudov,
Sergey I. Troyanov 
,
Ivan Godovikov,
Natalya E. Fedorova ,
Regina R. Klimova ,
Vasilina A. Sergeeva,
Larisa V. Kameneva,
Elizaveta S. Ershova,
Vyacheslav M. Martynenko,
Sandra Claes,
Alla A. Kushch ,
Svetlana V. Kostyuk,
Dominique Schols ,
Alexander F. Shestakov
and other authors.
,
Ivan Godovikov,
Natalya E. Fedorova ,
Regina R. Klimova ,
Vasilina A. Sergeeva,
Larisa V. Kameneva,
Elizaveta S. Ershova,
Vyacheslav M. Martynenko,
Sandra Claes,
Alla A. Kushch ,
Svetlana V. Kostyuk,
Dominique Schols ,
Alexander F. Shestakov
and other authors.
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Abstract
We report an “inversed” Arbuzov reaction of C60Ar5Cl with P(OR)3 producing C60Ar5R with an excellent selectivity.