Published in
Royal Society of Chemistry, Chemical Communications, 61(55), p. 8947-8950, 2019
DOI: 10.1039/c9cc04716f
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Synthesis of an enantiopure scorpionate ligand by a nucleophilic addition to a ketenimine and a zinc initiator for the isoselective ROP of rac-lactide
Journal article published in 2019 by
Manuel Honrado,
Sonia Sobrino 
,
Juan Fernández-Baeza ,
Luis F. Sánchez-Barba ,
Andrés Garcés ,
Agustín Lara-Sánchez ,
Ana M. Rodríguez
,
Juan Fernández-Baeza ,
Luis F. Sánchez-Barba ,
Andrés Garcés ,
Agustín Lara-Sánchez ,
Ana M. Rodríguez
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Abstract
The first example of nucleophilic addition of an organolithium to a ketenimine to prepare an enantiopure NNN-heteroscorpionate ligand is reported. Its utility to induce chirality is verified via preparation of two new zinc complexes, producing highly isotactic poly(lactide)s.