Published in
Royal Society of Chemistry, Chemical Communications, 52(55), p. 7506-7509, 2019
DOI: 10.1039/c9cc03321a
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Redox active [Pd2L4]4+ cages constructed from rotationally flexible 1,1′-disubstituted ferrocene ligands
Journal article published in 2019 by
Roan A. S. Vasdev 
,
James A. Findlay ,
Anna L. Garden ,
James D. Crowley
,
James A. Findlay ,
Anna L. Garden ,
James D. Crowley
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Abstract
Two new ferrocene-containing [Pd2(LFc)4]4+(X−)4 (where X− = BF4− or SbF6−) self-assembled cages were synthesised from the known, rotationally flexible, 1,1′-bis(3-pyridylethynyl)ferrocene ligand (LFc). The cages were shown to bind neutral and anionic guest molecules and displayed reversible redox activity.