Published in
Royal Society of Chemistry, Journal of Materials Chemistry A: materials for energy and sustainability, 19(7), p. 11944-11952, 2019
DOI: 10.1039/c9ta01188a
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Electrocatalytic reduction of CO2 by two-dimensional transition metal porphyrin sheets
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Abstract
The first transition metal series TM–PP monolayer catalysts exhibit excellent catalytic performance during the process of electroreduction of CO2. The products have 2e− CO (Sc, Mn and Ni), HCOOH (Cr, Fe, Co, Cu and Zn), 8e− CH4 (Ti and V), and the overpotential of the reaction can be as low as 0.127 V.