Published in
Royal Society of Chemistry, Dalton Transactions, 18(48), p. 5923-5932, 2019
DOI: 10.1039/c8dt04740e
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Sulfur substitution in a Ni(cyclam) derivative results in lower overpotential for CO2 reduction and enhanced proton reduction
Journal article published in 2019 by
P. Gerschel,
K. Warm,
E. R. Farquhar,
U. Englert 
,
M. L. Reback,
D. Siegmund ,
K. Ray ,
U.-P. Apfel
,
M. L. Reback,
D. Siegmund ,
K. Ray ,
U.-P. Apfel
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Abstract
N/S replacement in Ni-cyclam complexes highlights the importance of biologically relevant sulfur ligands in the CO2 and proton reduction.