Published in
Royal Society of Chemistry, Dalton Transactions, 13(48), p. 4333-4340, 2019
DOI: 10.1039/c9dt00313d
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Simple and reactive Ir(i) N-heterocyclic carbene complexes for alkyne activation
Journal article published in 2019 by
Mark R. D. Gatus 
,
Indrek Pernik ,
Joshua A. Tompsett,
Samantha C. Binding,
Matthew B. Peterson,
Barbara A. Messerle
,
Indrek Pernik ,
Joshua A. Tompsett,
Samantha C. Binding,
Matthew B. Peterson,
Barbara A. Messerle
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Abstract
Two simple unsymmetrical monometallic Ir(i) complexes with an N-heterocyclic carbene ligand were effective catalysts for C–X (X = N or O) and Si–N bond formation reactions compared to an analogous Ir(i) bimetallic complex.