Published in
Royal Society of Chemistry, Green Chemistry, 6(21), p. 1390-1395, 2019
DOI: 10.1039/c8gc03595d
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A ppm level Rh-based composite as an ecofriendly catalyst for transfer hydrogenation of nitriles: triple guarantee of selectivity for primary amines
Journal article published in 2019 by
Lei Liu 
,
Jifan Li,
Yongjian Ai,
Yuhong Liu,
Jialiang Xiong,
Hongdong Wang,
Yijun Qiao,
Wenrui Liu,
Shanchao Tan,
Shaofei Feng,
Kunpeng Wang,
Hongbin Sun ,
Qionglin Liang
,
Jifan Li,
Yongjian Ai,
Yuhong Liu,
Jialiang Xiong,
Hongdong Wang,
Yijun Qiao,
Wenrui Liu,
Shanchao Tan,
Shaofei Feng,
Kunpeng Wang,
Hongbin Sun ,
Qionglin Liang
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Abstract
A 49 ppm Rh catalyst selectively transforms nitriles into primary amines with economical HCOOH and exhibits a TOF value of 6803 h−1.