Published in
Royal Society of Chemistry, Organic and Biomolecular Chemistry, 10(17), p. 2705-2714, 2019
DOI: 10.1039/c9ob00262f
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Convenient access to 5-membered cyclic iminium ions: evidence for a stepwise [4 + 2] cycloaddition mechanism
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Abstract
In situ generation and reaction of novel 5-membered N-tosyl cyclic α,β-unsaturated iminium ions from readily prepared stable precursors is demonstrated.