Published in
Royal Society of Chemistry, Journal of Materials Chemistry A: materials for energy and sustainability, 10(7), p. 5685-5701, 2019
DOI: 10.1039/c8ta10610j
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STA-27, a porous Lewis acidic scandium MOF with an unexpected topology type prepared with 2,3,5,6-tetrakis(4-carboxyphenyl)pyrazine
Journal article published in 2019 by
Ram R. R. Prasad,
Sarah E. Seidner,
David B. Cordes 
,
Magdalena M. Lozinska ,
Daniel M. Dawson ,
Megan J. Thompson,
Tina Düren ,
Kristina K. Chakarova,
Mihail Y. Mihaylov,
Konstantin I. Hadjiivanov ,
Frank Hoffmann ,
Alexandra M. Z. Slawin ,
Sharon E. Ashbrook ,
Matthew L. Clarke ,
Paul A. Wright
,
Magdalena M. Lozinska ,
Daniel M. Dawson ,
Megan J. Thompson,
Tina Düren ,
Kristina K. Chakarova,
Mihail Y. Mihaylov,
Konstantin I. Hadjiivanov ,
Frank Hoffmann ,
Alexandra M. Z. Slawin ,
Sharon E. Ashbrook ,
Matthew L. Clarke ,
Paul A. Wright
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Abstract
The scandium-based tetracarboxylate MOF STA-27, which contains a 1D rod SBU comprised of Sc2O11 dimers, is an effective Lewis acid catalyst.