Published in
Royal Society of Chemistry, Dalton Transactions, 10(48), p. 3300-3313, 2019
DOI: 10.1039/c8dt04929g
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(Diphenylphosphino)alkylaldehyde affords hydride- or alkyl-[(diphenylphosphino)alkylacyl]rhodium(iii) or (diphenylphosphino)alkylester complexes: theoretical and experimental diastereoselectivity
Journal article published in 2019 by
Susan Azpeitia,
Montserrat Barquín,
Claudio Mendicute-Fierro,
Miguel A. Huertos 
,
Antonio Rodríguez-Diéguez ,
Jose M. Seco ,
Eider San Sebastian ,
Lourdes Ibarlucea,
María A. Garralda
,
Antonio Rodríguez-Diéguez ,
Jose M. Seco ,
Eider San Sebastian ,
Lourdes Ibarlucea,
María A. Garralda
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Abstract
Diastereoselective synthesis of 1 and 11 as predicted by DFT. 4 and 10 obtained without and lower diastereoselectivity than predicted.