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Royal Society of Chemistry, Chemical Communications, 19(55), p. 2809-2812, 2019

DOI: 10.1039/c9cc00432g

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Unusual ligand rearrangement: from N-phosphinoguanidinato to phosphinimine-amidinato compounds

Journal article published in 2019 by Rafael Fernández-Galán ORCID, Alberto Ramos ORCID, Estefanía Huergo, Antonio Antiñolo ORCID, Fernando Carrillo-Hermosilla ORCID, Antonio Rodríguez-Diéguez ORCID, Daniel García-Vivó ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

N,N′-Phosphinoguanidinate Al compounds rearrange under mild conditions to phosphinimine-amidinato derivatives via an unprecedented carbodiimide de-insertion followed by [3+2] cycloaddition.