Published in
Royal Society of Chemistry, Chemical Communications, 19(55), p. 2809-2812, 2019
DOI: 10.1039/c9cc00432g
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Unusual ligand rearrangement: from N-phosphinoguanidinato to phosphinimine-amidinato compounds
Journal article published in 2019 by
Rafael Fernández-Galán 
,
Alberto Ramos ,
Estefanía Huergo,
Antonio Antiñolo ,
Fernando Carrillo-Hermosilla ,
Antonio Rodríguez-Diéguez ,
Daniel García-Vivó
,
Alberto Ramos ,
Estefanía Huergo,
Antonio Antiñolo ,
Fernando Carrillo-Hermosilla ,
Antonio Rodríguez-Diéguez ,
Daniel García-Vivó
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Abstract
N,N′-Phosphinoguanidinate Al compounds rearrange under mild conditions to phosphinimine-amidinato derivatives via an unprecedented carbodiimide de-insertion followed by [3+2] cycloaddition.