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Royal Society of Chemistry, Physical Chemistry Chemical Physics, 5(21), p. 2234-2250, 2019

DOI: 10.1039/c8cp06910g

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Unprecedented O:⇔:O compression and H↔H fragilization in Lewis solutions

Journal article published in 2019 by Chang Q. Sun ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Charge injection in terms of protons, lone pairs, cations and anions by acid and base solvation mediates the HB network and properties of Lewis solutions through H↔H fragilization, O:⇔:O compression and polarization, ionic polarization and hydrating H2O dipolar screen shielding, anion–anion repulsion, compressed solvent H–O bond elongation and undercoordinated solute H–O bond contraction.