Published in
Royal Society of Chemistry, Dalton Transactions, 5(48), p. 1578-1585, 2019
DOI: 10.1039/c8dt04135k
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Diaqua-β-octaferrocenyltetraphenylporphyrin: a multiredox-active and air-stable 16π non-aromatic species
Journal article published in 2019 by
Rasha K. Al-Shewiki,
Marcus Korb 
,
Alexander Hildebrandt ,
Stefan Zahn ,
Sergej Naumov,
Roy Buschbeck,
Tobias Rüffer ,
Heinrich Lang
,
Alexander Hildebrandt ,
Stefan Zahn ,
Sergej Naumov,
Roy Buschbeck,
Tobias Rüffer ,
Heinrich Lang
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Abstract
Herein the synthesis and properties of the first β-octaferrocenyltetraphenylporphyrin, {TPPFc8(H2O)2}, in its extraordinary stable and non-aromatic 16π form are reported, showing seven separate reversible redox events.