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Royal Society of Chemistry, Physical Chemistry Chemical Physics, 5(21), p. 2283-2294, 2019

DOI: 10.1039/c8cp05950k

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Symmetry controlled excited state dynamics

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Symmetry effects in internal conversion are studied by means of two isomeric cyclic tertiary aliphatic amines in a velocity map imaging (VMI) experiment on the femtosecond timescale. We conclude that lessening the symmetry of the molecule leads to loss of coherence after internal conversion between Rydberg states.