Published in
Royal Society of Chemistry, Chemical Communications, 5(55), p. 695-698, 2019
DOI: 10.1039/c8cc08792j
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Rhodium(iii) vs. cobalt(iii): a mechanistically distinct three-component C–H bond addition cascade using a Cp*RhIII catalyst
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Abstract
Rhodium(iii) vs. cobalt(iii) in three-component C–H bond additions: the RhIII-catalytic system constitutes a complementary access with the CoIII-catalytic system, which involved a different rate-determining step and catalytic cycle with a different scope of substrates.