Published in
Royal Society of Chemistry, Dalton Transactions, 1(48), p. 209-219, 2019
DOI: 10.1039/c8dt04278k
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Synthesis and ligand substitution reactions of κ4-B,S,S′,S′′-ruthenaboratranes
Journal article published in 2019 by
Mark R. St.-J. Foreman 
,
Anthony F. Hill ,
Chenxi Ma,
Never Tshabang,
Andrew J. P. White
,
Anthony F. Hill ,
Chenxi Ma,
Never Tshabang,
Andrew J. P. White
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Abstract
Ruthenaboratranes of the form [Ru(CO)L{κ4-B(mt)3}] (mt = N-methimazolyl) arise via substitution of the PPh3 ligand in [Ru(CO)(PPh3){κ4-B(mt)3}] by L (L = PMe2Ph, PMe3, P(OMe)3, P(OEt)3, P(OPh)3) or reactions of [RuCl(R)(CO)Ln] (R = Ph, CHCHPh; n = 2, L = PCy3; n = 3, L = P(OMe)3, PMe2Ph) with Na[HB(mt)3].