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Royal Society of Chemistry, Dalton Transactions, 1(48), p. 209-219, 2019

DOI: 10.1039/c8dt04278k

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Synthesis and ligand substitution reactions of κ4-B,S,S′,S′′-ruthenaboratranes

Journal article published in 2019 by Mark R. St.-J. Foreman ORCID, Anthony F. Hill ORCID, Chenxi Ma, Never Tshabang, Andrew J. P. White
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Ruthenaboratranes of the form [Ru(CO)L{κ4-B(mt)3}] (mt = N-methimazolyl) arise via substitution of the PPh3 ligand in [Ru(CO)(PPh3){κ4-B(mt)3}] by L (L = PMe2Ph, PMe3, P(OMe)3, P(OEt)3, P(OPh)3) or reactions of [RuCl(R)(CO)Ln] (R = Ph, CHCHPh; n = 2, L = PCy3; n = 3, L = P(OMe)3, PMe2Ph) with Na[HB(mt)3].