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Royal Society of Chemistry, Dalton Transactions, 48(47), p. 17257-17265, 2018

DOI: 10.1039/c8dt03652g

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Slow spin crossover in bis-meridional Fe2+ complexes through spin-state auto-adaptive N6/N8 coordination

Journal article published in 2018 by Holm Petzold ORCID, Gerald Hörner ORCID, Linda Schnaubelt, Tobias Rüffer ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The X-factor: Exchange of pyridine (X = N) for phenyl (X = CH) substituents renders the coordination number of Fe2+ complexes spin-state dependent. Slow spin-state exchange emerges through kinetic and thermodynamic stabilization of the N6(+2) high-spin state.