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Royal Society of Chemistry, Journal of Materials Chemistry C Materials for optical and electronic devices, 46(6), p. 12652-12659, 2018

DOI: 10.1039/c8tc02374c

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Synthesis of Bi2−2xSb2xS3 (0 ≤ x ≤ 1) solid solutions from solventless thermolysis of metal xanthate precursors

Journal article published in 2018 by Tahani Alqahtani, Malik Dilshad Khan ORCID, Daniel J. Kelly, Sarah J. Haigh ORCID, David J. Lewis ORCID, Paul O’Brien ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Tris(O-ethylxanthate)bismuth(iii) (1) and tris(O-ethylxanthate)antimony(iii) (2) were synthesized and used as precursors for the preparation of Bi2−2xSb2xS3 alloys (x = 0, 0.2, 0.4, 0.6, 0.8 and 1) using melt reactions.