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Royal Society of Chemistry, Dalton Transactions, 42(47), p. 14893-14896, 2018

DOI: 10.1039/c8dt03851a

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Confluence of disparate carbido chemistries: [WRuAu2(μ-C)2Cl2(CO)2(PCy3)2(Tp*)]

Journal article published in 2018 by Anders Reinholdt, Jesper Bendix ORCID, Anthony F. Hill ORCID, Richard A. Manzano
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The reaction of [Ru(CAuCl)Cl2(PCy3)2] with [W(CSnnBu3)(CO)2(Tp*)] (obtained from [W(CBr)(CO)2(Tp*)], nBuLi and ClSnnBu3) affords the heterotetrametallic bis(carbido) complex [WRuAu2(μ-C)2Cl3(CO)2(PCy3)2(Tp*)] in which the two distinct μ-carbido ligands adopt linear and T-shaped geometry at carbon.