Published in
Royal Society of Chemistry, Journal of Materials Chemistry C Materials for optical and electronic devices, 3(7), p. 718-724
DOI: 10.1039/c8tc05131c
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Benzoselenadiazole and benzotriazole directed electrophilic C–H borylation of conjugated donor–acceptor materials
Journal article published in 2019 by
Barada P. Dash 
,
Iain Hamilton ,
Daniel J. Tate ,
Daniel L. Crossley,
Ji-Seon Kim ,
Michael J. Ingleson ,
Michael L. Turner
,
Iain Hamilton ,
Daniel J. Tate ,
Daniel L. Crossley,
Ji-Seon Kim ,
Michael J. Ingleson ,
Michael L. Turner
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Abstract
Borylative fusion of BSe and BTz containing donor–acceptor oligomers gives fused boracycles with a reduction in the energy of the LUMO by up to 0.65 eV. This leads to a red shift in emission of ca. 200 nm and the use of these materials for the fabrication of NIR OLEDs.