Pursuing reliable thermal analysis techniques for energetic materials: decomposition kinetics and thermal stability of dihydroxylammonium 5,5′-bistetrazole-1,1′-diolate (TKX-50)

Muravyev, Nikita V.; Monogarov, Konstantin A.; Asachenko, Andrey F.; Nechaev, Mikhail S.; Ananyev, Ivan V.; Fomenkov, Igor V.; Kiselev, Vitaly G.; Pivkina, Alla N.

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Royal Society of Chemistry, Physical Chemistry Chemical Physics, 1(19), p. 436-449

DOI: 10.1039/c6cp06498a

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Pursuing reliable thermal analysis techniques for energetic materials: decomposition kinetics and thermal stability of dihydroxylammonium 5,5′-bistetrazole-1,1′-diolate (TKX-50)

Journal article published in 2017 by Nikita V. Muravyev, Konstantin A. Monogarov, Andrey F. Asachenko, Mikhail S. Nechaev

, Ivan V. Ananyev, Igor V. Fomenkov, Vitaly G. Kiselev

, Alla N. Pivkina

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Abstract

Reliable kinetics of thermolysis for a novel explosive dihydroxylammonium 5,5′-bistetrazole-1,1′-diolate (TKX-50) was obtained using a variety of thermoanalytical and kinetic methods and verified by modeling of adiabatic self-heating.

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Pursuing reliable thermal analysis techniques for energetic materials: decomposition kinetics and thermal stability of dihydroxylammonium 5,5′-bistetrazole-1,1′-diolate (TKX-50)

Abstract