Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics, 35(20), p. 22915-22925
DOI: 10.1039/c8cp03955k
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Mechanistic details of ethylene polymerization reaction using methallyl nickel(ii) catalysts
Journal article published in 2018 by
Daniela E. Ortega,
Diego Cortés-Arriagada 
,
Alejandro Toro-Labbé
,
Alejandro Toro-Labbé
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Abstract
We present a mechanistic study of the ligand functionalization of bulky boron co-activators on neutral methallyl Ni(ii) catalysts for polyethylene production. This provides a blueprint for the development and design of catalysts with a high degree of tunability in a more efficient way.