Published in

Royal Society of Chemistry, Dalton Transactions, 24(46), p. 7791-7799

DOI: 10.1039/c7dt01199g

Links

Tools

Export citation

Search in Google Scholar

Normal-to-abnormal rearrangement of an N-heterocyclic carbene with a silylene transition metal complex

Journal article published in 2017 by Rajendra S. Ghadwal ORCID, Dennis Rottschäfer ORCID, Diego M. Andrada, Gernot Frenking ORCID, Christian J. Schürmann, Hans-Georg Stammler
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

Full text: Unavailable

Green circle
Preprint: archiving allowed
Upload
Orange circle
Postprint: archiving restricted
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

The NHC ligand of the complex 3-W undergoes normal-to-abnormal rearrangement on treatment with CsOH and yields the aNHC-complex 6-W, which is found to be 13.5 kcal mol−1 less stable than its normal counterpart.