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Royal Society of Chemistry, Chemical Communications, 5(53), p. 952-955

DOI: 10.1039/c6cc08392g

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Palladium-catalysed mono-α-alkenylation of ketones with alkenyl tosylates

Journal article published in 2017 by Yong Wu, Wai Chung Fu, Chien-Wei Chiang, Pui Ying Choy, Fuk Yee Kwong ORCID, Aiwen Lei ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The first general Pd-catalysed mono-α-alkenylation of ketones using alkenyl tosylates is reported. The combination of Pd(dba)2 and XPhos as the catalytic system exhibited excellent chemo- and monoselectivity at a relatively low catalyst loading (0.1–1.0 mol%).