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Royal Society of Chemistry, Polymer Chemistry, 2(3), p. 533-537, 2012

DOI: 10.1039/c2py00506a

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Branching out with aminals: microporous organic polymers from difunctional monomers

Journal article published in 2012 by Andrea Laybourn, Robert Dawson, Rob Clowes, Jonathan A. Iggo, Andrew I. Cooper, Yaroslav Z. Khimyak, Dave J. Adams ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Microporous organic polymers (MOPs) have been prepared via one-pot polycondensation reactions between aldehydes and amines. Primary amines were reacted with imines to produce porous polymers from A2 + B2 monomer combinations. The resulting networks exhibit BET surface areas in the range 500–600 m2 g−1. This approach opens up the possibility of synthesising MOPs using readily-available and inexpensive precursors.