Published in
Royal Society of Chemistry, Dalton Transactions, 34(46), p. 11145-11148
DOI: 10.1039/c7dt01993a
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A versatile route to homo- and hetero-bimetallic 5f–5f and 3d–5f complexes supported by a redox active ligand framework
Journal article published in 2017 by
Clément Camp 
,
Davide Toniolo,
Julie Andrez,
Jacques Pécaut,
Marinella Mazzanti
,
Davide Toniolo,
Julie Andrez,
Jacques Pécaut,
Marinella Mazzanti
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Abstract
The salt-elimination reaction of the complex [Na2U(bis-salophen)] with metal halides provides an entry to well-defined homobimetallic uranium–uranium and rare heterobimetallic uranium–cobalt and uranium–nickel complexes supported by a redox-active dinucleating ligand.