Published in
Royal Society of Chemistry, Dalton Transactions, 2(47), p. 357-366
DOI: 10.1039/c7dt04020b
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Is a strong axial crystal-field the only essential condition for a large magnetic anisotropy barrier? The case of non-Kramers Ho(iii) versus Tb(iii )
Journal article published in 2018 by
Sandeep K. Gupta 
,
Thayalan Rajeshkumar,
Gopalan Rajaraman ,
Ramaswamy Murugavel
,
Thayalan Rajeshkumar,
Gopalan Rajaraman ,
Ramaswamy Murugavel
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Abstract
This study highlights that although strong axiality holds the key for designing high temperature SMMs based on non-Kramers ions, the strength of the equatorial ligand field, although small, cannot be ignored.