Published in
Molecular Systems Design & Engineering, 1(3), p. 275-284
DOI: 10.1039/c8me00001h
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Unusual solvent polarity dependent excitation relaxation dynamics of a bis[p-ethynyldithiobenzoato]Pd-linked bis[(porphinato)zinc] complex
Journal article published in 2018 by
Jaehong Park 
,
Tae-Hong Park,
Louise E. Sinks,
Pravas Deria ,
Jiyong Park ,
Mu-Hyun Baik ,
Michael J. Therien
,
Tae-Hong Park,
Louise E. Sinks,
Pravas Deria ,
Jiyong Park ,
Mu-Hyun Baik ,
Michael J. Therien
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Abstract
A porphyrin dimer linked by a Pd(ii)-based linker displays unusual excited-state dynamics where solvent polarity steers singlet and triplet decay-channel population.