Published in
Royal Society of Chemistry, New Journal of Chemistry, 22(41), p. 13303-13318
DOI: 10.1039/c7nj02443f
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Competition between the donor and acceptor hydrogen bonds of the threads in the formation of [2]rotaxanes by clipping reaction
Journal article published in 2017 by
Marcos A. P. Martins 
,
Geórgia C. Zimmer ,
Leticia V. Rodrigues,
Tainára Orlando ,
Lilian Buriol,
Mateo Alajarin,
Jose Berna ,
Clarissa P. Frizzo,
Helio G. Bonacorso ,
Nilo Zanatta
,
Geórgia C. Zimmer ,
Leticia V. Rodrigues,
Tainára Orlando ,
Lilian Buriol,
Mateo Alajarin,
Jose Berna ,
Clarissa P. Frizzo,
Helio G. Bonacorso ,
Nilo Zanatta
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Abstract
The steric effect of thet-butyl group of 1′5′-thread prevents the formation of [2]rotaxane. On the other hand, the 1′3′-thread acts a template to obtain [2]rotaxanes.