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Royal Society of Chemistry, Physical Chemistry Chemical Physics, 32(19), p. 21304-21316

DOI: 10.1039/c7cp03350h

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Structural insights into the multinuclear speciation of tetravalent cerium in the tri-n-butyl phosphate–n-dodecane solvent extraction system

Journal article published in 2017 by Mark R. Antonio ORCID, Ross J. Ellis, Shanna L. Estes ORCID, Mrinal K. Bera ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Macroscopic phase behaviors in the liquid–liquid extraction are explained by microscopic, reverse micellar fluid structures containing tetranuclear Ce(iv) clusters revealed by use of X-ray spectroscopy and scattering of the light and dense organic phases.