Published in
Royal Society of Chemistry, Green Chemistry, 10(19), p. 2416-2426
DOI: 10.1039/c7gc00052a
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Photo-assisted water oxidation by high-nuclearity cobalt-oxo cores: tracing the catalyst fate during oxygen evolution turnover
Journal article published in 2017 by
M. Natali 
,
I. Bazzan,
S. Goberna-Ferrón ,
R. Al-Oweini,
M. Ibrahim,
B. S. Bassil,
H. Dau ,
F. Scandola,
J. R. Galán-Mascarós ,
U. Kortz,
A. Sartorel,
I. Zaharieva ,
M. Bonchio
,
I. Bazzan,
S. Goberna-Ferrón ,
R. Al-Oweini,
M. Ibrahim,
B. S. Bassil,
H. Dau ,
F. Scandola,
J. R. Galán-Mascarós ,
U. Kortz,
A. Sartorel,
I. Zaharieva ,
M. Bonchio
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Abstract
Cobalt-oxo cores with Co>9 enable oxygen evolution under visible light with diffusional electron transfer and 32 ET events in 60 ms.